In Science advances ; h5-index 0.0
Although monolayer transition metal dichalcogenides (TMDs) have direct bandgaps, the low room-temperature photoluminescence quantum yields (QYs), especially under high pump intensity, limit their practical applications. Here, we use a simple photoactivation method to enhance the room-temperature QYs of monolayer MoS2 grown on to silica micro/nanofibers by more than two orders of magnitude in a wide pump dynamic range. The high-density oxygen dangling bonds released from the tapered micro/nanofiber surface are the key to this strong enhancement of QYs. As the pump intensity increases from 10-1 to 104 W cm-2, our photoactivated monolayer MoS2 exhibits QYs from ~30 to 1% while maintaining high environmental stability, allowing direct lasing with greatly reduced thresholds down to 5 W cm-2. Our strategy can be extended to other TMDs and offers a solution to the most challenging problem toward the realization of efficient and stable light emitters at room temperature based on these atomically thin materials.
Liao Feng, Yu Jiaxin, Gu Zhaoqi, Yang Zongyin, Hasan Tawfique, Linghu Shuangyi, Peng Jian, Fang Wei, Zhuang Songlin, Gu Min, Gu Fuxing